The matchup between the Sun Devils and Spartans was the first in program history.
The win is the second against a ranked opponent for the pair, with the first coming with a 7-6 (5) victory over No. 19 Emile Hudd/Luke Hammond of Oklahoma State.
The bout between the Sun Devils and Buckeyes is the third matchup between the two teams in the last three seasons.
The win is the largest margin of victory for the Sun Devils since blanking Delaware 7-0 last April.
The home match is one of just two in the month of February for the Sun Devils.
No. 25 Sun Devil men's tennis' comeback fell short as they dropped their match with No. 14 Oklahoma State, 4-3, Sunday morning at the Goodfriend Tennis Center.